TY - JOUR
T1 - Pollutant Absorption as a Possible End-Of-Life Solution for Polyphenolic Polymers
AU - Sepperer, T.
AU - Neubauer, J.
AU - Eckardt, J.
AU - Schnabel, T.
AU - Petutschnigg, A.
AU - Tondi, G.
N1 - Cited By :16
Export Date: 14 December 2023
Correspondence Address: Tondi, G.; Forest Products Technology and Timber Constructions Department, Marktstraße 136a, Austria; email: [email protected]
Funding details: Interreg, InCIMa ITAT 1023
Funding text 1: Funding: The authors would like to acknowledge the support from European funding INTERREG Italy–Austria for the project InCIMa ITAT 1023.
References: Pala, A., Tokat, E., Color removal from cotton textile industry wastewater in an activated sludge system with various additives (2002) Water Res, 36, pp. 2920-2925; Gurung, M., Adhikari, B.B., Kawakita, H., Ohto, K., Inoue, K., Alam, S., Recovery of Au(III) by using low cost adsorbent prepared from persimmon tannin extract (2011) Chem. Eng. J, 174, pp. 556-563; Kawakita, H., Abe, M., Inoue, J.I., Ohto, K., Harada, H., Inoue, K., Selective gold recovery using orange waste (2009) Sep. Sci. Technol, 44, pp. 2797-2805; Parajuli, D., Kawakita, H., Kajiyama, K., Ohto, K., Harada, H., Inoue, K., Recovery of gold from hydrochloric acid by using lemon peel gel (2008) Sep. Sci. Technol, 43, pp. 2363-2374; Parajuli, D., Kawakita, H., Inoue, K., Ohto, K., Kajiyama, K., Persimmon peel gel for the selective recovery of gold (2007) Hydrometallurgy, 87, pp. 133-139; Alila, S., Boufi, S., Removal of organic pollutants from water by modified cellulose fibres (2009) Ind. Crops Prod, 30, pp. 93-104; Janoš, P., Coskun, S., Pilařová, V., Rejnek, J., Removal of basic (Methylene Blue) and acid (Egacid Orange) dyes from waters by sorption on chemically treated wood shavings (2009) Bioresour. Technol, 100, pp. 1450-1453; Uddin, M.T., Islam, M.A., Mahmud, S., Rukanuzzaman, M., Adsorptive removal of methylene blue by tea waste (2009) J. Hazard. Mater, 164, pp. 53-60; Wang, G., Chen, Y., Xu, G., Pei, Y., Effective removing of methylene blue from aqueous solution by tannins immobilized on cellulose microfibers (2019) Int. J. Biol. Macromol, 129, pp. 198-206; Cao, J., Zhang, J., Zhu, Y., Wang, S., Wang, X., Lv, K., Novel Polymer Material for Efficiently Removing Methylene Blue, Cu(II) and Emulsified Oil Droplets fromWater Simultaneously (2018) Polymers (Basel), 10, p. 1393; Yu, K., Wang, D., Wang, Q., Yu, K., Wang, D., Wang, Q., Tough and Self-Healable Nanocomposite Hydrogels for Repeatable Water Treatment (2018) Polymers (Basel), 10, p. 880; Ge, M., Xi, Z., Zhu, C., Liang, G., Hu, G., Jamal, L., Alam, S., M., J (2019) Preparation and Characterization of Magadiite-Magnetite Nanocomposite with Its Sorption Performance Analyses on Removal of Methylene Blue from Aqueous Solutions. Polymers (Basel), 11, p. 607; Delforno, T.P., Moura, A.G.L., Okada, D.Y., Sakamoto, I.K., Varesche, M.B.A., Microbial diversity and the implications of sulfide levels in an anaerobic reactor used to remove an anionic surfactant from laundry wastewater (2015) Bioresour. Technol, 192, pp. 37-45; Karray, F., Mezghani, M., Mhiri, N., Djelassi, B., Sayadi, S., Scale-down studies of membrane bioreactor degrading anionic surfactants wastewater: Isolation of new anionic-surfactant degrading bacteria (2016) Int. Biodeterior. Biodegradation, 114, pp. 14-23; Hussain, S., Malik, A.H., Iyer, P.K., Highly Precise Detection, Discrimination, and Removal of Anionic Surfactants over the Full pH Range via Cationic Conjugated Polymer: An Efficient Strategy to Facilitate Illicit-Drug Analysis (2015) ACS Appl. Mater. Interfaces, 7, pp. 3189-3198; Ali, I., Asim, M., Khan, T.A., Low cost adsorbents for the removal of organic pollutants from wastewater (2012) J. Environ. Manage, 113, pp. 170-183; Zietzschmann, F., Stützer, C., Jekel, M., Granular activated carbon adsorption of organic micro-pollutants in drinking water and treated wastewater-Aligning breakthrough curves and capacities (2016) Water Res, 92, pp. 180-187; Quideau, S., Deffieux, D., Douat-Casassus, C., Pouységu, L., Plant Polyphenols: Chemical Properties, Biological Activities, and Synthesis (2011) Angew. Chemie Int. Ed, 50, pp. 586-621; Pizzi, A., Tondi, G., Pasch, H., Celzard, A., Matrix-assisted laser desorption/ionization time-of-flight structure determination of complex thermoset networks: Polyflavonoid tannin-furanic rigid foams (2008) J. Appl. Polym. Sci, 110, pp. 1451-1456; Sánchez-Martín, J., Beltrán-Heredia, J., Carmona-Murillo, C., Adsorbents from Schinopsis balansae: Optimisation of significant variables (2011) Ind. Crops Prod, 33, pp. 409-417; Sánchez-Martín, J., Beltrán-Heredia, J., Delgado-Regaña, A., Rodríguez-González, M.A., Rubio-Alonso, F., Optimization of tannin rigid foam as adsorbents for wastewater treatment (2013) Ind. Crops Prod, 49, pp. 507-514; Sánchez-Martín, J., González-Velasco, M., Beltrán-Heredia, J., Acacia mearnsii de Wild Tannin-Based Flocculant in Surface Water Treatment (2009) J. Wood Chem. Technol, 29, pp. 119-135; Sánchez-Martín, J., González-Velasco, M., Beltrán-Heredia, J., Gragera-Carvajal, J., Salguero-Fernández, J., Novel tannin-based adsorbent in removing cationic dye (Methylene Blue) from aqueous solution (2010) Kinetics and equilibrium studies. J. Hazard. Mater, 174, pp. 9-16; Inoue, K., Paudyal, H., Nakagawa, H., Kawakita, H., Ohto, K., Selective adsorption of chromium(VI) from zinc(II) and other metal ions using persimmon waste gel (2010) Hydrometallurgy, 104, pp. 123-128; Tondi, G., Oo, C.W., Pizzi, A., Trosa, A., Thevenon, M.F., Metal adsorption of tannin based rigid foams (2009) Ind. Crops Prod, 29, pp. 336-340; Link, M., Kolbitsch, C., Tondi, G., Ebner, M., Wieland, S., Petutschnigg, A., Formaldehyde-free tannin-based foams and their use as lightweight panels (2011) BioResources, 6, pp. 4218-4228; Tondi, G., Link, M., Kolbitsch, C., Lesacher, R., Petutschnigg, A., Pilot plant up-scaling of tannin foams (2016) Ind. Crops Prod, 79, pp. 211-218; Grishechko, L.I., Amaral-Labat, G., Szczurek, A., Fierro, V., Kuznetsov, B.N., Pizzi, A., Celzard, A., New tannin-lignin aerogels (2013) Ind. Crops Prod, 41, pp. 347-355; Tondi, G., Pizzi, A., Tannin-based rigid foams: Characterization and modification (2009) Ind. Crops Prod, 29, pp. 356-363; Kolbitsch, C., Link, M., Petutschnigg, A., Wieland, S., Tondi, G., Microwave Produced Tannin-furanic Foams (2012) J. Mater. Sci. Res, p. 1; Sepperer, T., Petutschnigg, A., Bogner, B., Oostingh, G., Hernandez-Ramos, F., Labidi, J., Tondi, G., Purification of industrial tannin extract through simple solid-liquid extractions-submitted (2018) Ind. Crops Prod; Missio, A.L., Tischer, B., dos Santos, P.S.B., Codevilla, C., de Menezes, C.R., Barin, J.S., Haselein, C.R., Petutschnigg, A., Analytical characterization of purified mimosa (Acacia mearnsii) industrial tannin extract: Single and sequential fractionation (2017) Sep. Purif. Technol, 186, pp. 218-225; Sepperer, T., Tondi, G., Tannin-furanic foams from purified extracts (2018) Proceedings of the 5th International Conference on Processing Technologies for the Forest and Biobased Industries, , PTF-BPI, Freising/Munich, Germany, 20-21 September; Tondi, G., Link, M., Kolbitsch, C., Gavino, J., Luckeneder, P., Petutschnigg, A., Herchl, R., Van Doorslaer, C., Lignin-based Foams: Production Process and Characterization (2016) BioResources, p. 11; Shan, W., Ren, F., Zhang, Q., Wan, L., Xing, Z., Lou, Z., Xiong, Y., Enhanced adsorption capacity and selectivity towards molybdenum in wastewater by a persimmon tannin waste based new adsorbent (2015) J. Chem. Technol. Biotechnol, 90, pp. 888-895; Jiang, X., Liu, Y., Wu, Y., Tan, H., Meng, F., Wang, Y.S., Li, M., Qian, Y., Analysis of accumulation patterns and preliminary study on the condensation mechanism of proanthocyanidins in the tea plant [Camellia sinensis] (2015) Sci. Rep, p. 5; Bhuyan, A.K., On the mechanism of SDS-induced protein denaturation (2010) Biopolymers, 93, pp. 186-199; Marrakchi, S., Maibach, H.I., Sodium Lauryl Sulfate-Induced Irritation in the Human Face: Regional and Age-Related Differences (2006) Skin Pharmacol. Physiol, 19, pp. 177-180; Hayashi, K., A rapid determination of sodium dodecyl sulfate with methylene blue (1975) Anal. Biochem, 67, pp. 503-506; Banfi, D., Patiny, L., Resurrecting and Processing NMR Spectra On-line (2008) Chim. Int. J. Chem, 62, pp. 280-281; Steinbeck, C., Krause, S., Kuhn, S., NMRShiftDBConstructing a Free Chemical Information System with Open-Source Components (2003) J. Chem. Inf. Comput. Sci, 43, pp. 1733-1739; Castillo, A.M., Patiny, L., Wist, J., Fast and accurate algorithm for the simulation of NMR spectra of large spin systems (2011) J. Magn. Reson, 209, pp. 123-130; Dogan, M., Abak, H., Alkan, M., Adsorption of methylene blue onto hazelnut shell: Kinetics, mechanism and activation parameters (2009) J. Hazard. Mater, 164, pp. 172-181; Lin, J., Zhao, G., Preparation and characterization of high surface area activated carbon fibers from lignin (2016) Polymers (Basel), p. 8; Liu, W., Guo, R., Interaction between flavonoid, quercetin and surfactant aggregates with different charges (2006) J. Colloid Interface Sci, 302, pp. 625-632; Tondi, G., Link, M., Oo, C.W., Petutschnigg, A., Asimple approach to distinguish classic, formaldehyde-free tannin based rigid foams by ATR FT-IR. (2015) J Spectrosc, p. 2015; Tondi, G., Petutschnigg, A., Middle infrared (ATR FT-MIR) characterization of industrial tannin extracts (2015) Ind. Crops Prod, 65, pp. 422-428; Taylor, P., Ricci, A., Olejar, K.J., Parpinello, G.P., Kilmartin, P.A., (2015) Application of Fourier Transform Infrared (FTIR) Spectroscopy in the Characterization of Tannins, 50, pp. 37-41; Tondi, G., Tannin-Based Copolymer Resins: Synthesis and Characterization by Solid State 13C NMR and FT-IR Spectroscopy (2017) Polymers (Basel), 9, p. 223; Tondi, G., Sepperer, T., Cefarin, N., Musso, M., Reyer, A., Vaccari, L., Multi-technique investigation of poly-furfuryl alcohol-submitted (2019) Macromolucules; Pizzi, A., (1994) Tannin based Wood Adhesives Technology. In Advanced Wood Adhesives Technology, p. 304. , Decker: New York, NY, USA; Pizzi, A., Stephanou, A., A comparative C13 NMR study of polyflavonoid tannin extracts for phenolic polycondensates (1993) J. Appl. Polym. Sci, 50, pp. 2105-2113
PY - 2019/5/20
Y1 - 2019/5/20
N2 - Tannin- and lignin-furanic foams are natural porous materials that have attracted high interest in the scientific and industrial communities for their high thermal and fire-resistant properties. However, no interesting solutions have been proposed for the management of their end-life as yet. In this study, the phenolic-furanic powders derived from the foams were analyzed for their capacity to remove different pollutants like neutral, cationic, and anionic organic molecules from wastewater. It was observed that the macromolecules produced from initially bigger fractions were more suitable to remove methylene blue and sodium dodecyl sulfate (SDS) while contained absorptions were observed for riboflavin. Acidified tannin powders were also prepared to understand the role of the flavonoid in the absorption mechanism. The latter showed outstanding absorption capacity against all of the tested pollutants, highlighting the key-role of the flavonoid fraction and suggesting the limited contribution of the furanic part. All adsorbents were investigated through FT-IR and solid state 13C-NMR. Finally, the powders were successfully regenerated by simple ethanol washing, showing almost complete absorption recovery.
AB - Tannin- and lignin-furanic foams are natural porous materials that have attracted high interest in the scientific and industrial communities for their high thermal and fire-resistant properties. However, no interesting solutions have been proposed for the management of their end-life as yet. In this study, the phenolic-furanic powders derived from the foams were analyzed for their capacity to remove different pollutants like neutral, cationic, and anionic organic molecules from wastewater. It was observed that the macromolecules produced from initially bigger fractions were more suitable to remove methylene blue and sodium dodecyl sulfate (SDS) while contained absorptions were observed for riboflavin. Acidified tannin powders were also prepared to understand the role of the flavonoid in the absorption mechanism. The latter showed outstanding absorption capacity against all of the tested pollutants, highlighting the key-role of the flavonoid fraction and suggesting the limited contribution of the furanic part. All adsorbents were investigated through FT-IR and solid state 13C-NMR. Finally, the powders were successfully regenerated by simple ethanol washing, showing almost complete absorption recovery.
KW - Anionic surfactants
KW - Bio-based foams
KW - Cationic dyes
KW - Pollutant adsorbents
KW - Tannin polymer
KW - Tannin-furanic foam
KW - Wastewater treatments
KW - Cationic surfactants
KW - Dyes
KW - Flavonoids
KW - Pollution
KW - Polymers
KW - Porous materials
KW - Powders
KW - Sulfur compounds
KW - Tannins
KW - Wastewater treatment
KW - Absorption capacity
KW - Absorption mechanisms
KW - Absorption recovery
KW - Bio-based
KW - Fire-resistant properties
KW - Industrial communities
KW - Polyphenolic polymers
KW - Sodium dodecyl sulfate
KW - Anionic Compounds
KW - Cationic Compounds
UR - https://www.mendeley.com/catalogue/d114cc29-b289-3860-a080-a4229cfc7a34/
U2 - 10.3390/polym11050911
DO - 10.3390/polym11050911
M3 - Article
C2 - 31137598
SN - 2073-4360
VL - 11
JO - Polym.
JF - Polym.
IS - 5
ER -