TY - JOUR
T1 - Physical-Mechanical Properties of Light Bark Boards Bound with Casein Adhesives
AU - Urstöger, J.
AU - Kain, G.
AU - Prändl, F.
AU - Barbu, M.C.
AU - Kristak, L.
N1 - Export Date: 14 December 2023
Correspondence Address: Kain, G.; Department of Green Engineering and Circular Design, Markt 136 a, Austria; email: [email protected]
Funding details: Ministerstvo školstva, vedy, výskumu a športu Slovenskej republiky
Funding details: Vedecká Grantová Agentúra MŠVVaŠ SR a SAV, VEGA, 1/0714/21
Funding text 1: This research was supported by the Ministry of Education, Science, Research and Sport of the Slovak Republic, grant Nr. VEGA 1/0714/21.
References: Vaucher, H., (1997) Baumrinden: Aussehen, Struktur, Funktion, Eigenschaften, , Naturbuch-Verl., Augsburg, Germany; Kain, G., Barbu, M.-C., Teischinger, A., Musso, M., Petutschnigg, A., Substantial Bark Use as Insulation Material (2012) For. Prod. J, 62, pp. 480-487; Martin, R.E., Thermal properties of bark (1963) Forest Prod. J, pp. 419-426; Volz, K.-R., Herstellung und Eigenschaften von Fichten-, Kiefern- und Buchrindenplatten (1973) Eur. J. Wood Prod, 31, pp. 221-229; Xing, C., Deng, J., Zhang, S.Y., Riedl, B., Cloutier, A., Impact of bark content on the properties of medium density fiberboard (MDF) in four species grown in eastern Canada (2006) For. Prod. J, 56, pp. 64-69; Kraft, R., Zur Chemisch-Technologischen Verwertung von Gebrauchten Holzwerkstoffen und Holzrinden (2007) Ph.D. Dissertation, , Universität Göttingen, Göttingen, Germany; Kain, G., Güttler, V., Barbu, M.-C., Petutschnigg, A., Richter, K., Tondi, G., Density related properties of bark insulation boards bonded with tannin hexamine resin (2014) Eur. J. Wood Prod, 72, pp. 417-424; Urstöger, J., Barbu, M.C., Pacher, T., Petutschnigg, A., Jorda, J., Tudor, E.M., Selected Properties of Cement Bound Spruce and Larch Bark Bio-Aggregates (2021) Polymers, 13. , 34960989; Braungart, M., McDonough, W., (2008) Die nächste industrielle Revolution: Die Cradle to Cradle-Community, , 2nd ed., Europäische Verl.-Anst, Hamburg, Germany; Frihart, C.R., Introduction to Special Issue: Wood Adhesives: Past, Present, and Future (2015) For. Prod. J, 65, pp. 4-8; Krug, D., Tobisch, S., Einsatz von Proteinen als Bindemittel für Holzwerkstoffe (2010) Eur. J. Wood Prod, 68, pp. 289-301; Kain, G., Güttler, V., Lienbacher, B., Barbu, M.C., Petutschnigg, A., Richter, K., Tondi, G., Effects of different Flavonoid Extracts in optimizing Tannin-glued Bark Insulation Boards (2015) Wood Fiber Sci, 47, pp. 258-269; Antov, P., Savov, V., Neykov, N., Sustainable bio-based adhesives for eco-friendly wood composites a review (2020) Wood Res, 65, pp. 51-62; Pizzi, A., Stracke, P., Trosa, A., Industrial tannin/hexamine low-emission exterior particleboards (1997) Eur. J. Wood Prod, 55, p. 168; Guo, M., Wang, G., Milk Protein Polymer and Its Application in Environmentally Safe Adhesives (2016) Polymers, 8; Solt, P., Konnerth, J., Gindl-Altmutter, W., Kantner, W., Moser, J., Mitter, R., van Herwijnen, H.W., Technological performance of formaldehyde-free adhesive alternatives for particleboard industry (2019) Int. J. Adhes. Adhes, 94, pp. 99-131; Herzog, A., Kerschbaumer, T., Schwarzenbrunner, R., Barbu, M.-C., Petutschnigg, A., Tudor, E.M., Efficiency of High-Frequency Pressing of Spruce Laminated Timber Bonded with Casein Adhesives (2021) Polymers, 13. , 34883739; Hussin, M.H., Abd Latif, N.H., Hamidon, T.S., Idris, N.N., Hashim, R., Appaturi, J.N., Brosse, N., Fatriasari, W., Latest advancements in high-performance bio-based wood adhesives: A critical review (2022) J. Mater. Res. Technol, 21, pp. 3909-3946; Cesprini, E., Causin, V., de Iseppi, A., Zanetti, M., Marangon, M., Barbu, M.C., Tondi, G., Renewable Tannin-Based Adhesive from Quebracho Extract and Furfural for Particleboards (2022) Forests, 13; Jorda, J., Cesprini, E., Barbu, M.-C., Tondi, G., Zanetti, M., Král, P., Quebracho Tannin Bio-Based Adhesives for Plywood (2022) Polymers, 14; Chen, X., Pizzi, A., Zhang, B., Zhou, X., Fredon, E., Gerardin, C., Du, G., Particleboard bio-adhesive by glyoxalated lignin and oxidized dialdehyde starch crosslinked by urea (2022) Wood Sci. Technol, 56, pp. 63-85; Vitola, L., Gendelis, S., Sinka, M., Pundiene, I., Bajare, D., Assessment of Plant Origin By-Products as Lightweight Aggregates for Bio-Composite Bounded by Starch Binder (2022) Energies, 15; Gumowska, A., Kowaluk, G., Physical and Mechanical Properties of High-Density Fiberboard Bonded with Bio-Based Adhesives (2023) Forests, 14; Ebnesajjad, S., Landrock, A.H., (2014) Characteristics of Adhesive Materials: Adhesives Technology Handbook, , Elsevier, Amsterdam, The Netherlands; Fay, P.A., History of adhesive bonding (2005) Adhesive Bonding: Science, Technology and Applications, , Adams R.D., (ed), CRC Press, Boca Raton, FL, USA, Cambridge, UK; Kollmann, F., (1955) Technologie des Holzes und der Holzwerkstoffe, , 2nd ed., Springer, Berlin/Heidelberg, Germany; Sutermeister, E., Brühl, E., (1932) Das Kasein: Chemie und Technische Verwertung, , Springer, Berlin/Heidelberg, Germany; Habenicht, G., (2002) Kleben—Grundlagen, Technologien, Anwendungen, , 4th ed., Springer, Berlin/Heidelberg, Germany; Reddy, A.B., Manjula, B., Sudhakar, K., Sivanjineyulu, V., Jayaramudu, T., Sadiku, E.R., Polyethylene/Other Biomaterials-based Biocomposites and Bionanocomposites (2016) Polyethylene-Based Biocomposites and Bionanocomposites, pp. 279-314. , Visakh P.M., Lüftel S., (eds), Wiley & Sons Ltd., Hoboken, NJ, USA; Horne, D.S., Casein micelle structure: Models and muddles (2006) Curr. Opin. Colloid Interface Sci, 11, pp. 148-153; McMahon, D.J., Oommen, B.S., Supramolecular structure of the casein micelle (2008) J. Dairy Sci, 91, pp. 1709-1721. , 18420601; Kain, G., Tudor, E.M., Barbu, M.-C., Bark Thermal Insulation Panels: An Explorative Study on the Effects of Bark Species (2020) Polymers, 12. , 32961694; Schwarzenbrunner, R., Development of Sustainable and Waterproof Casein Glue Formulations—Application on Biodegradable Skis (2019) Bachelor Thesis, , Salzburg University of Alied Sciences, Kuchl, Austria; (2006) EN 827:2006, , Adhesives—Determination of Conventional Solids Content and Constant Mass Solids Content, European Committee for Standardization, Brussels, Belgium; (2005) EN 326-1:2005, , Wood-Based Panels—Sampling and Cutting of Test Pieces, European Committee for Standardization, Brussels, Belgium; (2005) EN 323:2005, , Wood-Based Panels—Determination of Density, European Committee for Standardization, Brussels, Belgium; (2005) EN 322:2005, , Wood-Based Panels—Determination of Moisture Content, European Committee for Standardization, Brussels, Belgium; (2005) EN 317:2005, , Particleboards and Fibreboards—Determination of Swelling Thickness after Immersion Water, European Committee for Standardization, Brussels, Belgium; (2005) EN 319:2005, , Particleboards and Fibreboards—Determination of Tensile Strength Perpendicular to the Plane of the Board, European Committee for Standardization, Brussels, Belgium; (2005) EN 310:2005, , Wood-Based Panels—Determination of Modulus of Elasticity Bending and of Bending Strength, European Committee for Standardization, Brussels, Belgium; (2023) EN 29469:2023, , Thermal Insulating Products for Building Alications—Determination of Compression Behaviour, European Committee for Standardization, Brussels, Belgium; Backhaus, K., Erichson, B., Plinke, W., Weiber, R., (2011) Multivariate Analysemethoden: Eine Anwendungsorientierte Einführung, , 13th ed., Springer, Berlin/Heidelberg, Germany; Kuckartz, U., Rädiker, S., Ebert, T., Schehl, J., (2013) Statistik: Eine Verständliche Einführung, , VS Verlag für Sozialwissenschaften, Wiesbaden, Germany; (2010) EN 10456:2010, , Building Materials and Products—Hygrothermal Properties—Tabulated Design Values and Procedures for Determining Declared and Design Thermal Values, European Committee for Standardization, Brussels, Belgium; Schwemmer, R., Teischinger, A., Konnerth, J., Tipplreither, C., Jutz, W., (2010) Entwicklung der Fertigungstechnologie für Rohrkolben-Dämmstoffe, , BMVIT, Vienna, Austria; Pfundstein, M., Rodolphi, A., Spitzner, M.H., Gellert, R., (2007) Dämmstoffe: Grundlagen, Materialien, Anwendungen, , Institut f. Internationale Architektur-Dokumentation, München, Germany; Gößwald, J., Barbu, M.-C., Petutschnigg, A., Tudor, E.M., Binderless Thermal Insulation Panels Made of Spruce Bark Fibres (2021) Polymers, 13
PY - 2023/9/10
Y1 - 2023/9/10
N2 - Based on the background of the limited availability of raw materials in the forestry and timber industry, increased attention applies to sawmill by-products and their potential for future applications. Within the present research, the suitability of a natural binder based on different casein sources, superficially lean curd with different lime ratios, for the production of bark insulation panels from larch bark (Larix decidua) in fraction 12.5–4.0 mm with densities below 500 kg/m³ were discussed and physical and mechanical properties evaluated. In order to obtain a benchmark, control boards bound with powdery casein and urea-formaldehyde resin were fabricated. The evaluation of physical-mechanical characteristics indicated the lean curd panels to be competitive with the references and commercially available insulation materials, whereby higher values could be achieved consistently with a lower lime content of 20% compared to 31%. The best moisture resistance and water absorption were observed with a lime ratio of 31%, whilst thickness swelling and mechanical characteristics were best with a lime content of 20%. Particularly with regard to mechanical properties, panels containing a low proportion of lime in the lean curd blends delivered convincing results, e.g., with an average IB of 0.19 N/mm2, MOR of 1.43 N/mm2 and C of 1.70 N/mm2. In terms of thickness swelling, lean curd adhesives generated unsurpassed values of approximately 11% compared to the casein and urea-formaldehyde references. Additionally, as described in the relevant literature, a considerable influence of density on the mechanical behavior of composite materials was observed. Partly, the lime content significantly influenced the panel properties. The study proved that natural binders based on lean curd and lime are suitable for the production of bark insulation boards and represent a serious alternative to synthetic, oil-based adhesive systems. The results are promising with regard to the market situation due to the availability and pricing of raw materials and technical requirements and demonstrated great potential for further research efforts.
AB - Based on the background of the limited availability of raw materials in the forestry and timber industry, increased attention applies to sawmill by-products and their potential for future applications. Within the present research, the suitability of a natural binder based on different casein sources, superficially lean curd with different lime ratios, for the production of bark insulation panels from larch bark (Larix decidua) in fraction 12.5–4.0 mm with densities below 500 kg/m³ were discussed and physical and mechanical properties evaluated. In order to obtain a benchmark, control boards bound with powdery casein and urea-formaldehyde resin were fabricated. The evaluation of physical-mechanical characteristics indicated the lean curd panels to be competitive with the references and commercially available insulation materials, whereby higher values could be achieved consistently with a lower lime content of 20% compared to 31%. The best moisture resistance and water absorption were observed with a lime ratio of 31%, whilst thickness swelling and mechanical characteristics were best with a lime content of 20%. Particularly with regard to mechanical properties, panels containing a low proportion of lime in the lean curd blends delivered convincing results, e.g., with an average IB of 0.19 N/mm2, MOR of 1.43 N/mm2 and C of 1.70 N/mm2. In terms of thickness swelling, lean curd adhesives generated unsurpassed values of approximately 11% compared to the casein and urea-formaldehyde references. Additionally, as described in the relevant literature, a considerable influence of density on the mechanical behavior of composite materials was observed. Partly, the lime content significantly influenced the panel properties. The study proved that natural binders based on lean curd and lime are suitable for the production of bark insulation boards and represent a serious alternative to synthetic, oil-based adhesive systems. The results are promising with regard to the market situation due to the availability and pricing of raw materials and technical requirements and demonstrated great potential for further research efforts.
KW - bark boards
KW - casein
KW - insulation material
KW - lime
KW - natural binder–lean curd
KW - tree bark
KW - absorption
KW - adhesion
KW - bark
KW - composite
KW - formaldehyde
KW - insulation
KW - swelling
KW - urea
UR - https://www.mendeley.com/catalogue/7e00bff3-59cf-30c8-b57d-8d7b8685d191/
U2 - 10.3390/su151813530
DO - 10.3390/su151813530
M3 - Article
SN - 2071-1050
VL - 15
JO - Sustainability
JF - Sustainability
IS - 18
ER -