TY - JOUR
T1 - Larch Wood Residues Valorization through Extraction and Utilization of High Value-Added Products
AU - Wagner, K.
AU - Musso, M.
AU - Kain, S.
AU - Willför, S.
AU - Petutschnigg, A.
AU - Schnabel, T.
N1 - Cited By :8
Export Date: 14 December 2023
Correspondence Address: Schnabel, T.; Department of Forest Products Technology and Timber Constructions, Marktstraße 136a, Austria; email: [email protected]
Funding details: European Cooperation in Science and Technology, COST, FP 1407
Funding details: European Regional Development Fund, ERDF
Funding text 1: Differences in wood extractives from various resources of larch wood, sound and dead were observed by a GC-MS method. Sound knotwood can provide a greater extraction yield than dead knotwood were observed by a GC-MS method. Sound knotwood can provide a greater extraction knotwood and larch wood, mainly sapwood with a small amount of heartwood, from the outer part of yield than dead knotwood and larch wood, mainly sapwood with a small amount of heartwood, from the logs, while more resin acids and larixol can be extracted from dead knotwood samples compared the outer part of the logs, while more resin acids and larixol can be extracted from dead knotwood to the sound knotwood and larch wood samples. samples compared to the sound knotwood and larch wood samples. The results from the GC-MS were used to analyze three various spectroscopy methods for the The results from the GC-MS were used to analyze three various spectroscopy methods for the potential of the characterization of wood extractives and identification of the three wood types. With all potential of the characterization of wood extractives and identification of the three wood types. With vibrational spectroscopy used, chemical differences between the wood and knotwood were observed all vibrational spectroscopy used, chemical differences between the wood and knotwood were and can be used to fulfil various research tasks. Moreover, the methods of multivariate statistics were observed and can be used to fulfil various research tasks. Moreover, the methods of multivariate applied to analyze materials by using the score plot and loadings of the PC analysis. These results statistics were applied to analyze materials by using the score plot and loadings of the PC analysis. demonstrate that a classification of various wood tissues based on the different chemical components These results demonstrate that a classification of various wood tissues based on the different chemical (e.g., polyphenols and lipophilic substances) is possible with fast, non-destructive measurement components (e.g., polyphenols and lipophilic substances) is possible with fast, non-destructive methods. The current unused wood chips for material use can be separated into different fractions, measurement methods. The current unused wood chips for material use can be separated into where the extraction yields of the target substance (e.g., taxifolin) are higher compared to the other different fractions, where the extraction yields of the target substance (e.g., taxifolin) are higher fractions. This method may serve as basis to establish guidelines for quality assurance control systems compared to the other fractions. This method may serve as basis to establish guidelines for quality of this new approach for material use to obtain the huge potential of bio-based products for innovative assurance control systems of this new approach for material use to obtain the huge potential of bio-applications and for further efforts in the upscale from laboratory to industrial conditions. based products for innovative applications and for further efforts in the upscale from laboratory to AinudthuosrtrCiaoln ctroinbudtiitoionns:s.Conceptualization, K.W. and S.T.; methodology, K.W., M.M. and S.K.; software, K.W. and S.K.; investigation, K.W., M.M., S.K. and S.W.; resources, M.M., S.W. and A.P.; writing—original draft preparation, K.S.; writing—review and editing, M.M., S.W. and T.S.; supervision, M.M. and S.W.; project administration, A.P. Author Contributions: conceptualization, K.W. and S.T.; methodology, K.W., M.M. and S.K.; software, K.W. and T.S.; funding acquisition, A.P. All authors have read and agreed to the published version of the manuscript. and S.K.; investigation, K.W., M.M., S.K. and S.W.; resources, M.M., S.W. and A.P.; writing—original draft preparation, K.S.; writing—review and editing, M.M., S.W. and T.S.; supervision, M.M. and S.W.; project Wirtschafts Service) and the region of Salzburg for the support in the development of the Salzburg Center for SmartadminiMaterials.stration, A.P. and T.S.; funding acquisition, A.P. All authors have read and agreed to the published version of the manuscript. Acknowledgments: Kerstin Wagner thanks the COST Action FP 1407 and the Johan Gadolin Process Chemistry Funding: This research was funded by EFRE (European Funds for Regional Development), AWS (Austria Wirtschafts Service) and the region of Salzburg for the support in the development of the Salzburg Center for sections. This may include administrative and technical support, or donations in kind (e.g., materials used Smart Materials.
Funding text 2: This research was funded by EFRE (European Funds for Regional Development), AWS (Austria Wirtschafts Service) and the region of Salzburg for the support in the development of the Salzburg Center for Smart Materials. KerstinWagner thanks the COST Action FP 1407 and the Johan Gadolin Process Chemistry Centre-Åbo Akademi University for the funding received through the Short Term Scientific Mission (STSM). In this section you can acknowledge any support given which is not covered by the author contribution or funding sections. This may include administrative and technical support, or donations in kind (e.g., materials used for experiments).
References: Pieratti, E., Paletto, A., Atena, A., Bernardi, S., Palm, M., Patzelt, D., Romagnoli, M., Grebenc, T., Environmental and climate change impacts of eighteen biomass-based plants in the alpine region: A comparative anaylsis (2019) J. Clean. Prod, 242; Chen, M., Luo, J., Shi, R., Zhang, J., Gao, Q., Li, J., Improved adhesion performance of soy protein-based adhesives with a larch tannin-based resin (2017) Polymers, 9, p. 408; Jarre, M., Petit-Boix, A., Priefer, C., Meyer, R., Leipold, S., Transforming the bio-based sector towards a circular economy-What can we learn from wood cascading? For (2020) Policy Econ; Keegan, D., Kretschmer, B., Elbersen, B., Panoutsou, C., Cascading use: A systematic approach to biomass beyond the energy sector (2013) Biofuels Bioprod. Biorefin, 7, pp. 193-206; Fengel, D., Wegener, G., (2003) Wood Chemistry Ultrastruture Rections;, , Verlag Kessel: Remagen, Germany; Zule, J., Cufar, K., Tisler, V., Hydrophilic extractives in heartwood of European larch (Larix decidua Mill.) (2016) Drvna Ind, 67, pp. 363-370; Hörhammer, H., van Heiningen, A., A larch biorefinery: Influence of washing and PS charge on pre-extraction PSAQ pulping (2012) BioResources, 7, pp. 3539-3554; Willför, S.M., Ahotupa, M.O., Hemming, J.E., Reunanen, M.H.T., Eklund, P.C., Sjöholm, R.E., Eckerman, C.S.E., Holmbom, B.R., Antioxidant activity of knotwood extractives and phenolic compounds of selected tree species (2003) J. Agric. Food Chem, 51, pp. 7600-7606; Willför, S.M., Hemming, J., Reunanen, M., Eckerman, C., Holmbom, B., Lignans and lipophilic extractives in Norway spruce knots and steamwood (2003) Holzforschung, 57, pp. 27-36; Willför, S.M., Hemming, J., Reunanen, M., Holmbom, B., Phenolic and lipophilic extractives in Scots pine knots and stemwood (2003) Holzforschung, 57, pp. 359-372; Laireiter, C.M., Schnabel, T., Köck, A., Stalzer, P., Petutschnigg, A., Oostingh, G.J., Hell, M., Active anti-microbial effects of larch and pine wood on four bacterial strains (2013) BioRescources, 9, pp. 273-281; Wagner, K., Roth, C., Willför, S., Musso, M., Petutschnigg, A., Oostingh, G.J., Schnabel, T., Identification of antibmicrobial compounds in different hydrophilic larch bark extracts (2019) BioRescources, 14, pp. 5807-5815; Välimaa, A.-L., Honkalampi-Hämäläinen, U., Pietarinen, S., Willför, S., Holmbom, B., von Wright, A., Antimicrobial and cytotoxic knotwood extracts and related pure compounds and their effects on food-associated microorganisms (2007) Int. J. Food Microbiol, 115, pp. 235-243; Bowyer, J.L., Shmulsky, R., Haygreen, J.G., (2003) Forest Products and Wood Science: An Introduction;, , Iowa State Press: Ames, IA, USA; Nisula, L., Wood extractives in conifers (2018) A Study of Stemwood and Knots of Industrially Important Species, , Ph.D. Thesis, Abo Akademi University, Turku, Finland; Faix, O., Classification of lignins from different botanical origins by FT-IR spectroscopy (1991) Holzforschung, 45, pp. 21-27; Schwanninger, M., Hinterstoisser, B., Gradingler, C., Messner, K., Fackler, K., Examination of spruce wood biodegradaed by Ceriporisopsis subvermispora using near and mid infrared spectroscopy (2004) J. Near Infrared Spectrosc, 12, pp. 397-409; Schnabel, T., Musso, M., Tondi, G., Univariate and multivariate analysis of tannin-impregnated wood species using vibrational spectroscopy (2014) Appl. Spectroc, 68, pp. 488-494; Wagner, K., Schnabel, T., Barbu, M.-C., Petutschigg, A., Analysis of selected properties of fibreboard panels manufactured from wood and leather using the near infrared spectroscopy (2015) Int. J. Spectrosc; Agarwal, U.P., Atalla, R.H., Vibrational spectroscopy (2010) Lignin and Lignans. Advances in Chemistry;, pp. 103-136. , Heiter, C., Dimmel, D.R., Schmidt, J.A., Eds.; CRC Press: Boca Raton, FL, USA; Musso, M., Oehem, K.L., Raman spectroscopy (2008) Lasers in Chemistry: Probing and Influencing Matter;, pp. 531-591. , Lackner, M., Ed.; Wiley-VCM: Weinheim, Germany; Belt, T., Keplinger, T., Hänninen, T., Rautkari, L., Cellular level distributions of Scots pine heartwood and knot heartwood extractives revealed by Raman spectroscopy imaging (2017) Ind. Crop. Prod, 108, pp. 327-335; Pretsch, E., Bühlmann, P., Badertscher, M., (2009) Structure Determination of Organic Compounds, pp. 207-335. , 4th ed.; Springer: Berling/Heidlberg, Germany; Wienhaus, H., Pilz, W., Seibt, H., Dässler, H.-G., Die Diterpene Larixylacetat and Larixol (1960) Chem. Berichte, 93, pp. 2625-2630; Gierlinger, N., Schwanninger, M., Hnterstoisser, B., Wimmer, R., Rapid determination of heartwood extractives in Larix sp. by means of Fourier transform near infrared spectroscopy (2002) J. Near Infrared Spectrosc, 10, pp. 203-214; Schwanninger, M., Rodrigues, J.C., Facker, K., A review of band assignsments in near infrared spectra of wodo and wood components (2011) J. Near Infrared Spectrosc, 19, pp. 287-308; Michell, A.J., Schimleck, L.R., NIR spectroscopy of wood from Eucalyptus globulus (1996) Appita J, 49, pp. 23-26; Barton, I.I.F.E., Himmelbach, D.S., Duckworth, J.H., Smith, M.J., Two-dimensional vibration spectroscopy: Correlation of Mid-and Near-Infrared region (1992) Appl. Spectrosc, 46, pp. 420-429
PY - 2020/2/6
Y1 - 2020/2/6
N2 - Many of current bio-based materials are not fully or partly used for material utilization, as the composition of their raw materials and/or possible applications are unknown. This study deals with the analysis of the wood extractives from three different tissue of larch wood: Sapwood mainly from outer part of the log, and sound knotwood as well as dead knotwood. The extractions were performed with an accelerated solvent extractor (ASE) using hexane and acetone/water. The obtained extracts were analyzed by gas chromatography coupled to mass spectrometry (GC-MS). Three various vibrational spectroscopy (FT-RAMAN, FT-IR and FT-NIR) methods reflect the information from the extracts to the chemical composition of the types of wood before the extraction processes. Multivariate data analysis of the spectra was used to obtain a better insight into possible classification methods. Taxifolin and kaempferol were found in larger amount in sound knotwood samples compared to larch wood with high percentage of sapwood and dead knotwood samples. While the extractions of dead knotwood samples yielded more larixol and resin acids than the other larch wood samples used. Based on the chemical composition, three lead compounds were defined for the classification of the different wood raw materials. The vibrational spectroscopy methods were applied to show their potential for a possible distinction of the three types of larch wood tissue. This new insight into the different larch wood extracts will help in the current efforts to use more environmentally friendly raw materials for innovative applications. The connection between the raw materials and extraction yields of the target values is important to transform the results from the laboratory to industry and consumer applications.
AB - Many of current bio-based materials are not fully or partly used for material utilization, as the composition of their raw materials and/or possible applications are unknown. This study deals with the analysis of the wood extractives from three different tissue of larch wood: Sapwood mainly from outer part of the log, and sound knotwood as well as dead knotwood. The extractions were performed with an accelerated solvent extractor (ASE) using hexane and acetone/water. The obtained extracts were analyzed by gas chromatography coupled to mass spectrometry (GC-MS). Three various vibrational spectroscopy (FT-RAMAN, FT-IR and FT-NIR) methods reflect the information from the extracts to the chemical composition of the types of wood before the extraction processes. Multivariate data analysis of the spectra was used to obtain a better insight into possible classification methods. Taxifolin and kaempferol were found in larger amount in sound knotwood samples compared to larch wood with high percentage of sapwood and dead knotwood samples. While the extractions of dead knotwood samples yielded more larixol and resin acids than the other larch wood samples used. Based on the chemical composition, three lead compounds were defined for the classification of the different wood raw materials. The vibrational spectroscopy methods were applied to show their potential for a possible distinction of the three types of larch wood tissue. This new insight into the different larch wood extracts will help in the current efforts to use more environmentally friendly raw materials for innovative applications. The connection between the raw materials and extraction yields of the target values is important to transform the results from the laboratory to industry and consumer applications.
KW - GC-MS
KW - Kaempferol
KW - Knotwood
KW - Larixol
KW - Taxifolin
KW - Vibrational spectroscopy
KW - Acetone
KW - Flavonoids
KW - Gas chromatography
KW - Lead compounds
KW - Mass spectrometry
KW - Multivariant analysis
KW - Spectroscopic analysis
KW - Spectrum analysis
KW - Tissue
KW - Wood products
KW - Extraction
UR - https://www.mendeley.com/catalogue/a71b9dca-dcd9-30f5-87d6-dd3261f8e359/
U2 - 10.3390/polym12020359
DO - 10.3390/polym12020359
M3 - Article
C2 - 32041295
SN - 2073-4360
VL - 12
JO - Polym.
JF - Polym.
IS - 2
ER -